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Mohemed Lakhdar, Belfar
- A Simple Group-Interaction Contribution Method for the Prediction of the Freezing Point of Ionic Liquids
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Authors
Khadra Mokadem
1,
Belfar Mohemed Lakhdar
2,
Kaniki Tumba
3,
Abdulqader Saad Abed
4,
Mourad Korichi
1
Affiliations
1 Kasdi Merbah Ouargla University, B.P. 511, 30000, Ouargla, Algeria ., IN
2 Kasdi Merbah Ouargla University, B.P. 511, 30000, Ouargla, Algeria, IN
3 Department of Chemical Engineering, Mangosuthu University of Technology, Durban, South Africa., IN
4 Ministry of water Resources, State commission on Operation of Irrigation and Drainage projects, Water Resources, El Anbar, Iraq., IN
1 Kasdi Merbah Ouargla University, B.P. 511, 30000, Ouargla, Algeria ., IN
2 Kasdi Merbah Ouargla University, B.P. 511, 30000, Ouargla, Algeria, IN
3 Department of Chemical Engineering, Mangosuthu University of Technology, Durban, South Africa., IN
4 Ministry of water Resources, State commission on Operation of Irrigation and Drainage projects, Water Resources, El Anbar, Iraq., IN
Source
Asian Journal of Research in Chemistry, Vol 15, No 6 (2022), Pagination: 404 - 408Abstract
A linear model based on group-interaction contributions is proposed for the estimation of the freezing temperature (Tf) of ionic liquids (ILs). This property is important for modelling solid-liquid equilibrium and selecting ionic liquids as reaction media among other things. A database of 66 experimental freezing points different ionic liquids was used to obtain all interaction contribution parameters and model constants. The database included various classes of ionic liquids and a wide range of cation and anion groups., with an average absolute relative deviation of 4,09% and a correlation coefficient of 0,93.
Keywords
Group-Interaction Contribution, Ionic Liquids, Freezing Temperature, Molecular Structure, Property Estimation.
References
- Villanueva J. S. M. Thermal Properties of Pure Ionic liquids, in: A.P.D.L.R.a.F.J.H. Fernandez (Ed.) Ionic Liquids in Separation Technology, Elsevier. 2014; ISBN: 9780444632623
- Plechkova N. V. Seddon K.R., Applications of ionic liquids in the chemical industry, Chemical Society Reviews. 2008; 37, 123150.doi.org/10.1039/B006677J
- Fox D. M. Gilman J.W. Morgan A.B. Shields J.R. Maupin P.H., Lyon R.E. De Long H.C. Trulove P.C. Flammability and thermal analysis characterization of imidazolium-based ionic liquids, Industrial & Engineering Chemistry Research. 2008; 47:6327-6332.DOI10.1021/ie800665u
- Rogers R. D. Seddon K.R. Ionic liquids--solvents of the future?, Science.2003;302:792-793.DOI: 10.1126/science.1090313
- Trulove P. C. Mantz R.A. Electrochemical properties of ionic liquids, in, Wiley-VCH: Morlenbach., 2003. ISBN 3-527-30612-9
- Dupont J. On the solid, liquid and solution structural organization of imidazolium ionic liquids, Journal of the Brazilian Chemical Society.2004;15:341-350. https://doi.org/10.1590/S010350532004000300002
- Schröder U. Wadhawan J. D. Compton R. G. Marken, F. Suarez P. A. Z. Consorti C. S Consorti. F. Roberto de Souzab and Dupont J. Water-induced accelerated ion diffusion: voltammetric studies in 1methyl-3-[2,6-(S)-dimethylocten-2-yl]imidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium tetrafluoroborate and hexafluorophosphate ionic liquids. J. New J. Chem. 2000;24:1009–1015.DOIhttps://doi.org/10.1039/B007172M
- Marrero‐MorejónJ. GaniR.Group-contribution based estimation of pure component properties, Fluid Phase Equilibria. 2001;183:183208.DOI:10.1016/S0378-3812(01)00431-9
- Pardillo-Fontdevila E. González-Rubio R. A group-interaction contribution approach. A new strategy for the estimation of physicochemical properties of branched isomers, Chemical Engineering Communications. 1998; 163:245-254.
- Zhang S. Sun N., He X. Lu X. Zhang X. Physical properties of ionic liquids: database and evaluation, Journal of physical and chemical reference data.. 2006. 35:1475-1517.https://doi.org/10.1063/1.2204959
- S. Zhang, X. Lu, X. Li, Q. Zhou, X. Zhang, S. Li Ionic Liquids: Physicochemical Properties, 1st Edition, Elsevier Science.2009.
- Lazzús J. A. A Group Contribution Method For Predicting The Freezing Point Of Ionic Liquids, Periodica Polytechnica Chemical Engineering. 2016; Doi: 10.3311/Ppce.9082. DOI: 10.3311/PPce.9082
- Constantinou L. Gani R. New group contribution method for estimating properties of pure compounds, AIChE Journal. 1994;40,1697-1710. DOI:10.1002/AIC.690401011
- Marrero‐Morejón J. Pardillo‐Fontdevila E. Estimation of pure compound properties using group‐interaction contributions, AIChE journal.,1999 ;45: 615-621. doi.org/10.1002/aic.690450318
- Mokadem K. Korichi M. Tumba K. A new group-interaction contribution method to predict the thermal decomposition temperature of ionic liquids, Original Research Article, Chemometrics and Intelligent Laboratory Systems.2016; 157:189-195.
- Mokadem K. Korichi M. Group - Interaction Contribution Approach for Prediction of Electrochemical Properties of Ionic Liquids, Computer Aided Chemical Engineerin. 2016;38:451-456. DOI: 10.1016/j.fluid.2020.112462 .